26559-57-9Relevant academic research and scientific papers
Copper-catalyzed N- and O-alkylation of amines and phenols using alkylborane reagents
Sueki, Shunsuke,Kuninobu, Yoichiro
supporting information, p. 1544 - 1547 (2013/06/26)
By the reaction of amines with alkylborane reagents in the presence of a catalytic amount of copper(II) acetate Cu(OAc)2 and di-tert-butyl peroxide, a cross-coupling reaction proceeded and alkylated amines were obtained in good to excellent yields. Phenols are also applicable for this reaction, and the corresponding alkyl aryl ethers were produced.
Efficient unimolecular deprotonation of aniline radical cations
Dombrowski, Gary W.,Dinnocenzo, Joseph P.,Zielinski, Paul A.,Farid, Samir,Wosinska, Zofia M.,Gould, Ian R.
, p. 3791 - 3800 (2007/10/03)
Deprotonation of the radical cations of aromatic amines, such as anilines, generally occurs much more slowly than other fragmentation reactions. Here we report a stereoelectronic effect involving twisting of the anilino group out of the plane of the benze
