265643-06-9Relevant academic research and scientific papers
Opposite π-face selectivity for the DMD and m-CPBA epoxidations of chiral 2,2-dimethyloxazolidine derivatives of tiglic amides: Control by steric interactions versus hydrogen bonding
Adam, Waldemar,Pastor, Aurelia,Peters, Karl,Peters, Eva-Maria
, p. 1019 - 1022 (2007/10/03)
A high extent but opposite sense in the diastereoselectivity has been observed for the DMD and m-CPBA epoxidations of the optically active tiglic amides (S)-1 with 2,2-dimethyloxazolidines as chiral auxiliaries. This unprecedented reversed π-facial differ
