26583-85-7Relevant academic research and scientific papers
Steric control of geminal Lewis pair behavior: Frustration induced dyotropic rearrangement
Dorkó, éva,Varga, Eszter,Gáti, Tamás,Holczbauer, Tamás,Pápai, Imre,Mehdi, Hasan,Soós, Tibor
supporting information, p. 1525 - 1528 (2014/07/08)
A series of methylene-linked boron/nitrogen geminal Lewis pairs were synthesized and the impacts of sterical effect on their chemical behavior were systematically investigated. Increasing the steric demand around the boron atom is manifested first by an incremental change in the structure of the resulting dative adducts. Accordingly, in the case of phenyl substituents (Alk 2NCH2BPh2), formation of head-to-tail dimers/oligomers was observed, while such an intermolecular association was avoided when o-tolyl moiety was introduced [Alk2NCH 2B(o-Tol)2], affording only an intramolecular dative complex. Further increase of sterical hindrance to a point (i.e. using mesityl substituents), however, caused a radical change in the structure; a dyotropic rearrangement occurred. Thus, steric interference induced a rearrangement in the geminal pair to relieve or minimize the frustration strain. Georg Thieme Verlag Stuttgart New York.
Ring Halogenations of Polyalkylbenzenes by Ionic Halides and Koser's Reagent
Bovonsombat, Pakorn,Djuardi, Elsa,Nelis, Edward Mc
, p. 2841 - 2844 (2007/10/02)
Ring chlorinations of polyalkylbenzenes such as mesitylene have been carried out at room temperature with LiCl or NaCl and stoichiometric amounts of Koser's reagent.Solvent range from water to methylene chloride.The procedures were extended to bromination and iodination.
