26583-85-7

Basic information

• Product Name: 2-bromo-4-chloro-1,3,5-trimethylbenzene
• Synonyms: 2-bromo-4-chloro-1,3,5-trimethylbenzene
• CAS NO: 26583-85-7
• Molecular Weight: 233.535
• Mol File: 26583-85-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2-bromo-4-chloro-1,3,5-trimethylbenzene(CAS DataBase Reference)
• NIST Chemistry Reference: 2-bromo-4-chloro-1,3,5-trimethylbenzene(26583-85-7)
• EPA Substance Registry System: 2-bromo-4-chloro-1,3,5-trimethylbenzene(26583-85-7)

Safety Data

• Hazardous Substances Data: 26583-85-7(Hazardous Substances Data)

Upstream product

• 108-67-8 1,3,5-trimethyl-benzene 
• 576-83-0 2,4,6-trimethylphenyl bromide 
• 1667-04-5 2-bromomesitylene 

Downstream Products

• 1632119-12-0 fluorobis(3-chloro-2,4,6-trimethylphenyl)borane 
• 26584-21-4 Methyl-3-chlor-2,4,6-trimethylbenzoat 
• 177969-47-0 3-chloro-2,4,6-trimethyl-benzoic acid 

Relevant articles and documents

Steric control of geminal Lewis pair behavior: Frustration induced dyotropic rearrangement

A series of methylene-linked boron/nitrogen geminal Lewis pairs were synthesized and the impacts of sterical effect on their chemical behavior were systematically investigated. Increasing the steric demand around the boron atom is manifested first by an incremental change in the structure of the resulting dative adducts. Accordingly, in the case of phenyl substituents (Alk 2NCH2BPh2), formation of head-to-tail dimers/oligomers was observed, while such an intermolecular association was avoided when o-tolyl moiety was introduced [Alk2NCH 2B(o-Tol)2], affording only an intramolecular dative complex. Further increase of sterical hindrance to a point (i.e. using mesityl substituents), however, caused a radical change in the structure; a dyotropic rearrangement occurred. Thus, steric interference induced a rearrangement in the geminal pair to relieve or minimize the frustration strain. Georg Thieme Verlag Stuttgart New York.