26623-27-8Relevant academic research and scientific papers
Tandem Radical Fragmentation/Cyclization of Guanidinylated Monosaccharides Grants Access to Medium-Sized Polyhydroxylated Heterocycles
González, Concepción C.,Santana, Andrés G.
supporting information, p. 8492 - 8495 (2020/11/18)
The fragmentation of anomeric alkoxyl radicals (ARF) and the subsequent cyclization promoted by hypervalent iodine provide an excellent method for the synthesis of guanidino-sugars. The methodology described herein is one of the few existing general metho
DERIVATIVES OF 6-DEOXY-L-TALOSE AND THE SYNTHESIS OF 6-DEOXY-2-O-(α-L-RHAMNOPYRANOSYL)-L-TALOSE
Aspinall, Gerald O.,Takeo, Ken'ichi
, p. 61 - 78 (2007/10/02)
Benzyl 6-deoxy-α-L-talopyranoside (10) has been synthesized and provides, after hydrogenolysis, an improved preparation of 6-deoxy-L-talose.Several partially substituted derivatives of the glycoside 10 have been prepared, including benzyl 6-deoxy-3,4-O-is
