26697-95-0

Basic information

• Product Name: ethyl α-deuteriodiazoacetate
• Synonyms: ethyl α-deuteriodiazoacetate
• CAS NO: 26697-95-0
• Molecular Weight: 115.096
• Mol File: 26697-95-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: ethyl α-deuteriodiazoacetate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl α-deuteriodiazoacetate(26697-95-0)
• EPA Substance Registry System: ethyl α-deuteriodiazoacetate(26697-95-0)

Safety Data

• Hazardous Substances Data: 26697-95-0(Hazardous Substances Data)

Upstream product

• 623-73-4 diazoacetic acid ethyl ester 
• 16576-95-7 Benzyldimethylundecylammonium chloride 

Downstream Products

• 80655-92-1 c-2-phenyl-1,2,t-3-trideuteriocyclopropanecarboxylic acid 
• 80594-21-4 C₁₀H₇⁽²⁾H₃O₂ 
• 80655-95-4 1,2,c-3-trideuterio-t-2-phenylcyclopropylmethanol 
• 80655-96-5 1,2,t-3-trideuterio-c-2-phenylcyclopropylmethanol 

Relevant articles and documents

Silver-promoted, palladium-catalyzed direct arylation of cyclopropanes: Facile access to spiro 3,3′-cyclopropyl oxindoles

The Pd-catalyzed, Ag(I)-mediated intramolecular direct arylation of cyclopropane C-H bonds is described. Various spiro 3,3′-cyclopropyl oxindoles can be obtained in good to excellent yields from easily accessible 2-bromoanilides. The kinetic isotope effect was determined and epimerization studies were conducted, suggesting that the formation of a putative Pd-enolate is not operative and that the reaction proceeds via a C-H arylation pathway.