26735-34-2Relevant academic research and scientific papers
METAL COMPLEXES IN ORGANIC SYNTHESIS-V ALKYLATIONS OF PENTANE-2,4-DIONE WITH ALLYLIC ALCOHOLS UNDER PALLADIUM CATALYSIS
Moreno-Manas, M.,Trius, A.
, p. 3009 - 3016 (2007/10/02)
Pentane-2,4-dione with allylic alcohols or benzyl alcohol with palladium catalysts gives high yields of C-monoalkylated diketones, arising mainly from reaction at the terminal end of the allylic system for alkyl monosubstituted allyl alcohols.The effect of the catalyst on the alcohols has been evaluated; rearrangements and disproportionations have been observed.
