267410-53-7Relevant academic research and scientific papers
Synthesis of (23R)- and (23S)-23H-isocalysterols, marine sterols with a cyclopropene moiety in the side chain
Kurek-Tyrlik, Alicja,Minksztym, Kazimierz,Wicha, Jerzy
, p. 1027 - 1036 (2007/10/03)
A synthesis of (23R)- and (23S)-23H-calysterols 2a and 2b from pregnanoic ester 10 is reported. Alkylation of 10 with dibromide 19b, followed by reduction of the carboethyloxy group to a methyl group, afforded (Z)-vinylic bromide 22. Dibromocyclopropanati
