267872-82-2

Upstream product

• 267873-04-1 (1R,2R,6R)-2-(tert-Butyl-dimethyl-silanyloxymethyl)-7,7-dimethyl-4-phenylselanyl-bicyclo[4.1.0]heptan-3-one 
• 267872-84-4 (1R,2R,6R)-2-Hydroxymethyl-7,7-dimethyl-4-phenylselanyl-bicyclo[4.1.0]heptan-3-one 
• 158831-18-6 2,2-Dimethyl-propionic acid (1R,2R,4R,6R,7R)-8,8-dimethyl-5-oxo-3-oxa-tricyclo[5.1.0.0^2,4]oct-6-ylmethyl ester 
• 267873-03-0 (1R,2R,6R)-2-(tert-Butyl-dimethyl-silanyloxymethyl)-7,7-dimethyl-bicyclo[4.1.0]heptan-3-one 
• 267873-05-2 (1R,2R,6R)-2-(tert-Butyl-dimethyl-silanyloxymethyl)-7,7-dimethyl-bicyclo[4.1.0]hept-4-en-3-one 
• 267872-79-7 (1R,2R,6R)-2-Hydroxymethyl-7,7-dimethyl-bicyclo[4.1.0]heptan-3-one 
• 267872-80-0 (1R,2R,6R)-2-Hydroxymethyl-7,7-dimethyl-bicyclo[4.1.0]hept-4-en-3-one 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 158831-19-7 2,2-Dimethyl-propionic acid (1R,2R,5S,6R)-5-hydroxy-7,7-dimethyl-3-oxo-bicyclo[4.1.0]hept-2-ylmethyl ester 

Downstream Products

• 267872-85-5 2,2-Dimethyl-propionic acid (1R,2R,5S,6R)-5-(tert-butyl-diphenyl-silanyloxy)-3-hydroxy-3-(methoxy-trimethylsilanyl-methyl)-7,7-dimethyl-bicyclo[4.1.0]hept-2-ylmethyl ester 
• 267872-93-5 (1S,2S,3R,5R,6R)-5-(tert-Butyl-dimethyl-silanyloxy)-2-[(E)-2-(tert-butyl-diphenyl-silanyloxymethyl)-4-(4-methoxy-benzyloxy)-but-1-enyl]-7,7-dimethyl-3-vinyl-bicyclo[4.1.0]heptane 
• 267872-94-6 (1S,2S,3R,5R,6R)-5-(tert-Butyl-dimethyl-silanyloxy)-2-[(E)-2-(tert-butyl-diphenyl-silanyloxymethyl)-4-nitro-but-1-enyl]-7,7-dimethyl-3-vinyl-bicyclo[4.1.0]heptane 
• 267872-96-8 (1S,2S,3R,5S,6R)-5-(tert-Butyl-dimethyl-silanyloxy)-2-[(E)-2-(tert-butyl-diphenyl-silanyloxymethyl)-4-nitro-but-1-enyl]-7,7-dimethyl-3-vinyl-bicyclo[4.1.0]heptane 
• 267873-02-9 (1S,2S,3R,5R,6R)-5-(tert-Butyl-dimethyl-silanyloxy)-2-[(E)-2-(tert-butyl-diphenyl-silanyloxymethyl)-4-iodo-but-1-enyl]-7,7-dimethyl-3-vinyl-bicyclo[4.1.0]heptane 
• 267872-92-4 2-[1-[(1S,2S,3R,5R,6R)-5-(tert-Butyl-dimethyl-silanyloxy)-7,7-dimethyl-3-vinyl-bicyclo[4.1.0]hept-2-yl]-meth-(E)-ylidene]-4-(4-methoxy-benzyloxy)-butyric acid methyl ester 
• 267872-86-6 2,2-Dimethyl-propionic acid (1S,2S,5S,6R)-5-(tert-butyl-diphenyl-silanyloxy)-3-[1-methoxy-meth-(E)-ylidene]-7,7-dimethyl-bicyclo[4.1.0]hept-2-ylmethyl ester 
• 267872-87-7 2,2-Dimethyl-propionic acid (1S,2S,3S,5S,6R)-5-(tert-butyl-diphenyl-silanyloxy)-3-dimethoxymethyl-7,7-dimethyl-bicyclo[4.1.0]hept-2-ylmethyl ester 
• 267872-89-9 2,2-Dimethyl-propionic acid (1S,2R,3R,5S,6R)-5-(tert-butyl-diphenyl-silanyloxy)-7,7-dimethyl-3-vinyl-bicyclo[4.1.0]hept-2-ylmethyl ester 
• 267872-88-8 2,2-Dimethyl-propionic acid (1S,2S,3S,5S,6R)-5-(tert-butyl-diphenyl-silanyloxy)-3-formyl-7,7-dimethyl-bicyclo[4.1.0]hept-2-ylmethyl ester 

Relevant academic research and scientific papers

An efficient method for the synthesis of versatile intermediates leading to 13-deoxy- and 9,13-dideoxyphorbols

An efficient method for the synthesis of versatile intermediates for biologically interesting 13-deoxy- and 9,13-dideoxyphorbol ester analogs is described. First, more efficient synthetic routes to the bicyclic ketones 7 and 8, which are well-known interm