26828-56-8

Basic information

• Product Name: 1,3-Cyclohexanedione, 2-methyl-2-(2-oxo-2-phenylethyl)-
• CAS NO: 26828-56-8
• Molecular Formula: C15H16O3
• Molecular Weight: 244.29
• Mol File: 26828-56-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1,3-Cyclohexanedione, 2-methyl-2-(2-oxo-2-phenylethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3-Cyclohexanedione, 2-methyl-2-(2-oxo-2-phenylethyl)-(26828-56-8)
• EPA Substance Registry System: 1,3-Cyclohexanedione, 2-methyl-2-(2-oxo-2-phenylethyl)-(26828-56-8)

Safety Data

• Hazardous Substances Data: 26828-56-8(Hazardous Substances Data)

Upstream product

• 70-11-1 α-bromoacetophenone 
• 504-02-9 1,3-cylohexanedione 
• 14073-26-8 2-(2-oxo-2-phenylethyl)cyclohexane-1,3-dione 
• 74-88-4 methyl iodide 
• 1193-55-1 2-methylcyclohexane-1,3-dione 

Downstream Products

• 91165-16-1 7a-Hydroxy-3a-methyl-2-phenyl-3,3a,5,6,7,7a-hexahydro-indol-4-one 
• 91165-23-0 1-Methyl-3-phenyl-7,8-dihydro-6H-indolizin-5-one 

Relevant articles and documents

THE SYNTHESIS AND CHEMISTRY OF AZOLENINES. PART 8. THE PAAL-KNORR REACTION WITH CYCLIC 2-(ACYLMETHYL)-2-ALKYL-1,3-DIKETONES: ISOLATION OF 1-ACYL-1H-PYRROLES VIA REARRANGEMENT

Treatment of cyclic 2-acylmethyl-2-alkyl-1,3-diketones with ammonium acetate under reflux in acetic acid gives moderate to high yields of 1-acyl-1H-pyrroles by rearrangement.Some of the cyclic diketones react quantitatively with liquid ammonia to yield 2-