26863-19-4Relevant academic research and scientific papers
Silver-promoted benzannulations of siloxyalkynes with pyridinium and isoquinolinium salts
Cabrera-Pardo, Jaime R.,Chai, David I.,Kozmin, Sergey A.
, p. 2495 - 2498 (2013)
We describe the development of efficient benzannulations of siloxyalkynes with pyridinium and isoquinolinium salts. Such reactions are successfully promoted by a stoichiometric amount of silver(I) benzolate under mild reaction conditions. This process proceeds via a formal inverse-electron demand Diels-Alder reaction, followed by fragmentation of the initially produced bicyclic adducts to deliver a range of synthetically useful phenols and naphthols. Copyright
