269053-97-6

Basic information

• Product Name: P(C₆H₅)4⁽¹⁺⁾*[Ho(C₆H₅C(O)NP(O)(OCH(CH₃)2)2)4]^(1-)=[P(C₆H₅)4][Ho(C₆H₅C(O)NP(O)(OCH(CH₃)2)2)4]
• CAS NO: 269053-97-6
• Molecular Weight: 1641.41
• Mol File: 269053-97-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: P(C₆H₅)4⁽¹⁺⁾*[Ho(C₆H₅C(O)NP(O)(OCH(CH₃)2)2)4]^(1-)=[P(C₆H₅)4][Ho(C₆H₅C(O)NP(O)(OCH(CH₃)2)2)4](CAS DataBase Reference)
• NIST Chemistry Reference: P(C₆H₅)4⁽¹⁺⁾*[Ho(C₆H₅C(O)NP(O)(OCH(CH₃)2)2)4]^(1-)=[P(C₆H₅)4][Ho(C₆H₅C(O)NP(O)(OCH(CH₃)2)2)4](269053-97-6)
• EPA Substance Registry System: P(C₆H₅)4⁽¹⁺⁾*[Ho(C₆H₅C(O)NP(O)(OCH(CH₃)2)2)4]^(1-)=[P(C₆H₅)4][Ho(C₆H₅C(O)NP(O)(OCH(CH₃)2)2)4](269053-97-6)

Safety Data

• Hazardous Substances Data: 269053-97-6(Hazardous Substances Data)

Upstream product

• 13598-41-9 holmium⁽³⁺⁾ 
• 2001-45-8 tetraphenyl phosphonium chloride 
• 131716-94-4 diisopropyl benzoylamidophosphate, sodium salt 

Relevant articles and documents

Synthesis and study of anionic lanthanide complexes with diisopropyl benzoylamidophosphate

Coordination compounds of the general formula Cat[LnL4], where Cat+ = NEt+4 (Ln = La, Ce-Er, Y); Cat+ = PPh+4 (Ln = La, Pr, Nd, Eu, Ho, Er) and several ordinary salts CatL, where Cat+ = Na+, PPh+4, SbPh+4; HL = C6H5C(O)NHP(O)[OCH(CH3)2] 2 (diisopropyl benzoylamidophosphate), are synthesized. The compounds are studied by IR, 1H NMR, 31P NMR, and electronic spectroscopy. From the IR and electronic spectroscopy data, the coordination mode of the ligand is established to be bidentate cyclic through the oxygen atoms of phosphoryl and carbonyl groups and the coordination geometry is proposed to be a square antiprism.