26930-28-9Relevant academic research and scientific papers
Radical isomerization via intramolecular ipso substitution of aryl ethers: Aryl translocation from oxygen to carbon
Lee, Eun,Lee, Chulbom,Tae, Jin Sung,Whang, Ho Sung,Li, Kap Sok
, p. 2343 - 2346 (2007/10/02)
Bromopropyl aryl ethers an converted to 3-arylpropanols under standard radical generating conditions in the presence of tributylstannane and AIBN. This rearrangement involves intramolecular ipso attack of the alkyl radicals which generates spiro cyclohexadienyl radical intermediates.
SYNTHESIS OF NOVEL MACROCYCLIC LACTONES WITH POTENTIAL PHARMACOLOGICAL ACTIVITY
Smith, Keith,Morris, Ian K.,Owen, Philip G.,Bass, Robert J.
, p. 77 - 84 (2007/10/02)
The total syntheses of four 14-membered ring lactones, (1a), (2a), (22), and (23), are described.The starting materials are the appropriate 2-hydroxybenzoic or (2-hydroxyphenyl)acetic acids and the final step in each case involves lactonization using a mo
