269715-89-1

Basic information

• Product Name: {[(E)-Benzyloxycarbonylimino]-[(2S,3R,4S,6R)-4-(tert-butyl-dimethyl-silanyloxy)-2-(tert-butyl-dimethyl-silanyloxymethyl)-3-methyl-6-(2-oxo-propyl)-piperidin-1-yl]-methyl}-carbamic acid benzyl ester
• Synonyms: {[(E)-Benzyloxycarbonylimino]-[(2S,3R,4S,6R)-4-(tert-butyl-dimethyl-silanyloxy)-2-(tert-butyl-dimethyl-silanyloxymethyl)-3-methyl-6-(2-oxo-propyl)-piperidin-1-yl]-methyl}-carbamic acid benzyl ester
• CAS NO: 269715-89-1
• Molecular Weight: 740.1
• Mol File: 269715-89-1.mol

Chemical Properties

• CAS DataBase Reference: {[(E)-Benzyloxycarbonylimino]-[(2S,3R,4S,6R)-4-(tert-butyl-dimethyl-silanyloxy)-2-(tert-butyl-dimethyl-silanyloxymethyl)-3-methyl-6-(2-oxo-propyl)-piperidin-1-yl]-methyl}-carbamic acid benzyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: {[(E)-Benzyloxycarbonylimino]-[(2S,3R,4S,6R)-4-(tert-butyl-dimethyl-silanyloxy)-2-(tert-butyl-dimethyl-silanyloxymethyl)-3-methyl-6-(2-oxo-propyl)-piperidin-1-yl]-methyl}-carbamic acid benzyl ester(269715-89-1)
• EPA Substance Registry System: {[(E)-Benzyloxycarbonylimino]-[(2S,3R,4S,6R)-4-(tert-butyl-dimethyl-silanyloxy)-2-(tert-butyl-dimethyl-silanyloxymethyl)-3-methyl-6-(2-oxo-propyl)-piperidin-1-yl]-methyl}-carbamic acid benzyl ester(269715-89-1)

Safety Data

• Hazardous Substances Data: 269715-89-1(Hazardous Substances Data)

Upstream product

• 269715-86-8 [(1S,2R,3S)-3-(tert-Butyl-dimethyl-silanyloxy)-1-(tert-butyl-dimethyl-silanyloxymethyl)-2-methyl-5-oxo-pentyl]-(2,2,2-trifluoro-acetyl)-carbamic acid benzyl ester 
• 269715-97-1 4-(tert-butyl-dimethyl-silanyloxy)-2-(tert-butyl-dimethyl-silanyloxymethyl)-3-methyl-6-(2-oxo-propyl)-piperidine-1-carboxylic acid benzyl ester 
• 269715-87-9 [(E)-(1S,2R,3S)-3-(tert-Butyl-dimethyl-silanyloxy)-1-(tert-butyl-dimethyl-silanyloxymethyl)-2-methyl-7-oxo-oct-5-enyl]-carbamic acid benzyl ester 
• 269715-81-3 [(1S,2R,3S)-1-(tert-Butyl-dimethyl-silanyloxymethyl)-3-hydroxy-2-methyl-hex-5-enyl]-carbamic acid benzyl ester 
• 269715-77-7 3-benzyloxycarbonylamino-4-(tert-butyl-dimethyl-silanyloxy)-2-methyl-butyric acid tert-butyl ester 
• 269715-80-2 [(1S,2R)-1-(tert-Butyl-dimethyl-silanyloxymethyl)-3-hydroxy-2-methyl-propyl]-carbamic acid benzyl ester 
• 269715-79-9 [(1S,2R)-1-(tert-Butyl-dimethyl-silanyloxymethyl)-2-methyl-3-oxo-propyl]-carbamic acid benzyl ester 
• 69739-34-0 t-butyldimethylsiyl triflate 
• 25508-20-7 N,N'-dibenzyloxycarbonyl-(S)-methyl-isothiourea 
• 269715-88-0 1-[4-(tert-butyl-dimethyl-silanyloxy)-6-(tert-butyl-dimethyl-silanyloxymethyl)-5-methyl-piperidin-2-yl]-propan-2-one 

Downstream Products

• 269715-91-5 (3R,4aS,6S,7R,8S)-1-[(E)-Benzyloxycarbonylimino]-6-(tert-butyl-dimethyl-silanyloxy)-8-(tert-butyl-dimethyl-silanyloxymethyl)-3,7-dimethyl-hexahydro-pyrido[1,2-c]pyrimidine-2-carboxylic acid benzyl ester 
• 269715-93-7 [6-(tert-butyl-dimethyl-silanyloxy)-8-(tert-butyl-dimethyl-silanyloxymethyl)-3,7-dimethyl-4,4a,5,6,7,8-hexahydro-3H-pyrido[1,2-c]pyrimidin-1-yl]-carbamic acid benzyl ester 
• 269715-94-8 ((3R,4aS,6S,7R,8S)-6-Hydroxy-8-hydroxymethyl-3,7-dimethyl-4,4a,5,6,7,8-hexahydro-3H-pyrido[1,2-c]pyrimidin-1-yl)-carbamic acid benzyl ester 
• 269715-90-4 {[(E)-Benzyloxycarbonylimino]-[(2S,3R,4S,6S)-4-(tert-butyl-dimethyl-silanyloxy)-2-(tert-butyl-dimethyl-silanyloxymethyl)-6-(2-hydroxy-propyl)-3-methyl-piperidin-1-yl]-methyl}-carbamic acid benzyl ester 

Relevant articles and documents

Stereoselective synthesis of a tricyclic guanidinium model of cylindrospermopsin

An 11-step enantioselective synthesis of the A-ring of cylindrospermopsin is described using an intramolecular conjugate addition as the key step to forming the piperidine ring. Further elaboration generates a tricyclic guanidine via a sequential double displacement strategy as a model for the cylindrospermopsin guanidinium core. (C) 2000 Elsevier Science Ltd.