270064-36-3

Upstream product

• 1099-45-2 ethyl (triphenylphosphoranylidene)acetate 
• 2774-29-0 (3aR,5R,6aR)-5-[(4R)-2,2-dimethyl-1,3-dioxolan-4-yl]-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxole 
• 4005-46-3 (1R)-1-[(3aR,5R,6aR)-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-5-yl]ethane-1,2-diol 
• 116431-47-1 (3aR,5R,6aR)-5-[(benzyloxy)methyl]-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxole 
• 14260-66-3 ((3αR,5S,6αR)-2,2-dimethyl-tetrahydrofuro[2,3-d][1,3]dioxol-5-yl)methanol 
• 14260-67-4 (3aR,5R,6aR)-2,2-dimethyl-3a,5,6,6a-tetrahydrofuro[2,3-d][1,3]dioxole-5-carbaldehyde 

Downstream Products

• 943763-57-3 ethyl (E)-3-{(4R,6R)-6-[(benzyloxy)methyl]-2,2-dimethyl-1,3-dioxan-4-yl}acrylate 
• 943763-54-0 (E)-3-{(4R,6R)-6-[(benzyloxy)methyl]-2,2-dimethyl-1,3-dioxan-4-yl}acrylaldehyde 
• 943763-58-4 (E)-3-{(4R,6R)-6-[(benzyloxy)methyl]-2,2-dimethyl-1,3-dioxan-4-yl}prop-2-en-1-ol 

Relevant academic research and scientific papers

Facile stereoselective synthesis of the C12-C24 fragment of macrolactin-A

A simple and efficient stereoselective synthesis of the C12-C24 fragment of the natural product macrolactin-A was achieved from D-glucose as the starting material and with use of the Wittig and modified Julia olefination reactions as key steps. Georg Thieme Verlag Stuttgart.

A general strategy for the formal synthesis of (-)-trans-kumausyne and total synthesis of (5R)-Hagen's gland lactones from diacetone-D-glucose

A general strategy for the formal synthesis of (-)-trans-kumausyne 1 via the bicyclic lactone (3aR,5R,6aR)-4 and total synthesis of (5R)-Hagen's gland lactones 2 and 3 via bicyclic lactone (3aR,5S,6aR)-5 starting from diacetone-D-glucose 6 is described. Syntheses of 4 and 5 were achieved by Wittig olefination-lactonization-Michael addition of the corresponding lactols 16 and 17, respectively. Copyright (C) 2000 Elsevier Science Ltd.