27032-09-3

Upstream product

• 504-02-9 1,3-cylohexanedione 
• 120-20-7 2-(3,4-dimethoxyphenyl)-ethylamine 

Downstream Products

• 107199-45-1 N-<2-(3,4-dimethoxyphenyl)ethyl>-N-(3-oxo-1-cyclohexen-1-yl)-α-(methylthio)acetamide 
• 79823-31-7 1-<2-(3,4-Dimethoxyphenyl)ethyl>-1,5,6,7-tetrahydro-2-methyl-3-phenyl-4H-indol-4-on 
• 107199-50-8 3,5,6,7-tetrahydro-1-<2-(3,4-dimethoxyphenyl)ethyl>-3-methylthio-1H-indole-2,4-dione 
• 107199-47-3 N-<2-(3,4-dimethoxyphenyl)ethyl>-N-(3-oxo-1-cyclohexen-1-yl)-α-(methylsulfinyl)acetamide 
• 1158819-79-4 C₂₅H₂₅NO₆ 
• 1412457-14-7 3-{2-[2-(1-hydroxyethyl)-4,5-dimethoxyphenyl]ethylamino}cyclohex-2-enone 
• 1412457-16-9 3-{2-[2-(hydroxyphenylmethyl)-4,5-dimethoxyphenyl]ethylamino}cyclohex-2-enone 
• 1412457-19-2 3-(6,7-dimethoxy-1-methyl-3,4-dihydro-1H-isoquinolin-2-yl)cyclohex-2-enone 
• 1412457-20-5 3-(6,7-dimethoxy-1-phenyl-3,4-dihydro-1H-isoquinolin-2-yl)cyclohex-2-enone 
• 944129-25-3 C₁₈H₂₃NO₄ 
• 944129-26-4 C₂₃H₂₅NO₄ 

Relevant academic research and scientific papers

Partially saturated indeno[1,2-b]indole derivatives via deoxygenation of heterocyclic α-hydroxy-N,O-hemiaminals

A series of 3-aminocyclohex-2-enones were reacted with indane-1,2,3-trione monohydrate (ninhydrin) yielding 4b,9b-dihydroxyindeno[ 1,2-b]indoles that were deoxygenated to indeno[1,2-b]indoles. Georg Thieme Verlag Stuttgart.

Heterocycles from Nitroalkenes, I. - Pyrroles via Michael Addition of Enamines

The principle of a general pyrrole synthesis via cyclising Michael addition of enamines to nitroalkenes is outlined.Condensation of the nitroalkene 7 with various enamines yields the pyrroles 9, 11, 12, 14, 15, 17, 18, 20, 22, 26, 27, 29, and 31.Reaction of 1-nitro-1,2-diphenylethene and the enamine 8 furnishes the pyrroloisoquinoline 32 while addition of 8 to 1-nitrocyclohexene is followed by ring closure to the indoloisoquinoline 33.The pyrrole 14 can also be prepared by multiple-component syntheses, further examples of which are the syntheses of the pyrroles 35, 36, 37, and 38.Scope and advantages of the presented pyrrole synthesis are discussed.