27044-93-5Relevant academic research and scientific papers
Telomerisation of buta-1,3-diene and methanol: Superiority of chromanyl-type phosphines in the dow process for the industrial production of 1-MOD
Tschan, Mathieu J.-L.,Launay, Helene,Hagen, Henk,Benet-Buchholz, Jordi,Van Leeuwen, Piet W.N.M.
experimental part, p. 8922 - 8928 (2011/09/16)
Butadiene and methanol were telomerised in the presence of palladium catalysts with ligands containing 8-diphenylphosphinochromane-like substituents at phosphorus. MonoXantphos and monoSPANphos afforded the most active, stable and selective catalysts known to date under commercially relevant production conditions for 1-methoxyocta-2,7-diene, the precursor to oct-1-ene.
