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27049-60-1

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27049-60-1 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 27049-60-1 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 2,7,0,4 and 9 respectively; the second part has 2 digits, 6 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 27049-60:
(7*2)+(6*7)+(5*0)+(4*4)+(3*9)+(2*6)+(1*0)=111
111 % 10 = 1
So 27049-60-1 is a valid CAS Registry Number.

27049-60-1Downstream Products

27049-60-1Relevant articles and documents

Visible-light enabled room-temperature dealkylative imidation of secondary and tertiary amines promoted by aerobic ruthenium catalysis

Yang, Dong,Shi, Jingqi,Chen, Jiaming,Jia, Xiaoqi,Shi, Cuiying,Ma, Lifang,Li, Ziyuan

, p. 18966 - 18973 (2021/06/03)

Employing sulfonyl azide as a nitrogen donor, a visible-light-enabled aerobic dealkylative imidation of tertiary and secondary amines involving C(sp3)-C(sp3) bond cleavage with moderate to excellent yields at room temperature is described. It has been demonstrated that this imidation could take place spontaneously upon visible-light irradiation, and could be facilitated considerably by a ruthenium photocatalyst and oxygen. An alternative mechanism to the previous aerobic photoredox pathway has also been proposed.

Electrochemically generatedN-iodoaminium species as key intermediates for selective methyl sulphonylimination of tertiary amines

Huang, Binbin,Yang, Chao,Zhou, Jia,Xia, Wujiong

supporting information, p. 5010 - 5013 (2020/05/18)

Reported herein is a straightforward protocol for approachingN-sulphonylamidinesviaan electricity-driven, iodine-mediated cross dehydrogenative condensation (CDC) between sulphonamides and tertiary amines, which features exclusive N-CH3selectivity for the amine partners. Mechanistic studies indicate that anin situgeneratedN-iodoaminium species serves as the key intermediate.

Visible-Light-Mediated Sulfonylimination of Tertiary Amines with Sulfonylazides Involving Csp3-Csp3 Bond Cleavage

Gui, Jiao,Xie, Haisheng,Jiang, Huanfeng,Zeng, Wei

, p. 2804 - 2807 (2019/04/30)

Visible-light-induced cross-coupling of arylsulfonyl azides with tertiaryamines in the presence of Eosin Y at room temperature has been achieved. This transformation features alkyl C-C bond cleavage and provides a green approach to N-sulfonylamidines under mild conditions.

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