270901-52-5

Basic information

• Product Name: 2,2,6,6-tetramethyl-1-(1-(4-methoxyphenyl)hex-5-enyloxy)piperidine
• Synonyms: 2,2,6,6-tetramethyl-1-(1-(4-methoxyphenyl)hex-5-enyloxy)piperidine
• CAS NO: 270901-52-5
• Molecular Weight: 345.525
• Mol File: 270901-52-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2,2,6,6-tetramethyl-1-(1-(4-methoxyphenyl)hex-5-enyloxy)piperidine(CAS DataBase Reference)
• NIST Chemistry Reference: 2,2,6,6-tetramethyl-1-(1-(4-methoxyphenyl)hex-5-enyloxy)piperidine(270901-52-5)
• EPA Substance Registry System: 2,2,6,6-tetramethyl-1-(1-(4-methoxyphenyl)hex-5-enyloxy)piperidine(270901-52-5)

Safety Data

• Hazardous Substances Data: 270901-52-5(Hazardous Substances Data)

Upstream product

• 2564-83-2 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical 
• 7031-93-8 2,2,6,6-tetramethylpiperidin-1-ol 

Relevant articles and documents

Factors influencing the C-O bond homolysis of alkoxyamines: Effects of H-bonding and polar substituents

The synthesis of various new trialkylhydroxylamines is described. The rate constant of the C-O bond cleavage of these new alkoxyamines has been measured. For example, C-O bond homolysis rates in a series of para-substituted TEMPO-styryl compounds TEMPO-CH(CH3)C6H5X 1a (p-MeO), 1b (p-Me), 1d (p-H), 1e (p-Br), and 1f (p-MeO2C) are presented. Furthermore, rate constants for the C-O bond cleavage of α-heteroaryl-substituted secondary alkoxyamines are discussed. A correlation by which the rate constant for the C-O bond cleavage of TEMPO-derived alkoxyamines can be predicted from the C-H BDEs of the corresponding alkanes is presented. Solvent effects as well as the effect of camphorsulfonic acid on the rate of the C-O bond homolysis are discussed. Finally, EPR and kinetic evidence show that alkoxyamines derived from nitroxides which are capable of intramolecular H-bonding undergo C-O bond cleavage faster than the corresponding non-H-bond-forming analogues.