270924-33-9

Upstream product

• 110-00-9 furan 
• 4356-77-8 1,6-di-O-acetyl-2,3,4-tri-O-benzyl-D-glucopyranose 

Downstream Products

• 270924-35-1 2-(2,3,4-tri-O-benzyl-6-deoxy-6-iodo-α-D-glucopyranosyl)furan 
• 270924-38-4 methyl (carba-5a methyl 2,3,4-tri-O-benzyl-β-D-idopyranosyl)uronate 
• 270924-37-3 2-[1D-(1,2,4,5/3)-2,3,4-tri-O-benzyl-5-O-methyl-2,3,4,5-tetrahydroxy-cyclohexyl]furan 
• 270924-32-8 2-(2,3,4-tri-O-benzyl-6-deoxy-α-D-xylo-hex-5-enopyranosyl)furan 
• 270924-36-2 2-[1-D-(1,2,4,5/3)-2,3,4-tri-O-benzyl-2,3,4,5-tetrahydroxy-cyclohexyl]furan 
• 270924-39-5 carba-5a methyl 2,3,4-tri-O-benzyl-β-D-idopyranoside 
• 270924-34-0 2-(2,3,4-tri-O-benzyl-α-D-glucopyranosyl)furan 

Relevant academic research and scientific papers

Synthesis of carba-β-D- and L-idopyranosides by rearrangement of unsaturated sugars

The triisobutylaluminium- (TIBAL) and titanium(IV)-promoted conversions of 6-deoxyhex-5-enopyranosides into highly functionalised cyclohexane derivatives provide intermediates for the synthesis of enantiomerically pure carba-sugars. The preparation of enantiomerically pure methyl carba-β-D-idopyranoside 1, methyl carba-β-L-idopyranoside 2 and 5'a-carbadisaccharide 3 is reported. Copyright (C) 2000 Elsevier Science Ltd.