271600-99-8Relevant articles and documents
2,4-Disubstituted thiazoles by regioselective cross-coupling or bromine-magnesium exchange reactions of 2,4-dibromothiazole
Gross, Stefan,Heuser, Stefan,Ammer, Carolin,Heckmann, Golo,Bach, Thorsten
experimental part, p. 199 - 206 (2011/03/18)
Cross-coupling reactions occur on 2,4-dibromothiazole preferentially at the more electron-deficient 2-position. This fact can be favorably used to prepare 2-substituted 4-bromothiazoles, which serve as precursors for 2,4-disubstituted thiazoles. Protocols