271780-37-1Relevant articles and documents
Preparation of optically active 15-epoxy-α-linolenic acids and their anti-rice blast fungus activities
Kato, Tadahiro,Nakai, Toshio,Ishimatu, Takayuki,Hoshikawa, Masahiro,Namai, Tsuneo
, p. 1353 - 1358 (2007/10/03)
By the action of NBS in aq. DME, α-linolenic acid was oxidized to 15- bromo-16-hydroxy-α-linolenic acid in 35% conversion yield. The bromohydrin was treated with lipase-PS and vinyl acetate to give the resolved acetate and bromohydrin. (15S,16R)- and (15R