272113-74-3

Upstream product

• 3162-96-7 4,6-O-benzylidene-1-O-methyl-α-D-glucopyranoside 
• 97-30-3 methyl-alpha-D-glucopyranoside 
• 1125-88-8 benzaldehyde dimethyl acetal 
• 3150-15-0 methyl 2,3-anhydro-4,6-O-benzilidene-α-D-mannopyranoside 
• 163580-26-5 methyl 4,6-O-benzylidene-3-C-cyano-3-deoxy-α-D-altropyranoside 

Downstream Products

• 957473-90-4 C₁₄H₁₁NO₃OCH₄O 
• 193271-77-1 (1S,2S,3S,5R,8R,10S,11S,12R)-10-methoxy-5-phenyl-4,6,9-trioxatetracyclo[10.2.1.0^2,11.0^3,8]pentadec-13-ene-2-carbaldehyde 
• 272113-75-4 methyl 3-cyano-2,3-dideoxy-α-D-erythro-hex-2-enopyranoside 
• 193271-74-8 methyl 4,6-O-benzylidene-2,3-dideoxy-3-C-formyl-α-D-erythro-hex-2-enopyranoside 

Relevant academic research and scientific papers

Preparation of 2-C- and 3-C-cyano-2-enopyranoside derivatives and their epoxidation

Methyl 4,6-O-benzylidene-2-C- and 3-C-cyano-2,3-dideoxy-d-erythro-hex-2-enopyranosides and -2-enitols were prepared and their epoxidation was performed.

Enantiospecific approach to a quinane skeleton related to pentalenolactones

A novel and general approach has been delineated for the enantiomerically pure synthesis of the angularly fused tricyclic system of the pentalenolactone family of compounds. D-Glucose is used as starting material and a diasteroselective Diels-Alder reaction sets the elements for the ring junctions.