27246-06-6

Basic information

• Product Name: 3-trityloxy-androstan-17-one
• Synonyms: 3-trityloxy-androstan-17-one
• CAS NO: 27246-06-6
• Molecular Weight: 532.766
• Mol File: 27246-06-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-trityloxy-androstan-17-one(CAS DataBase Reference)
• NIST Chemistry Reference: 3-trityloxy-androstan-17-one(27246-06-6)
• EPA Substance Registry System: 3-trityloxy-androstan-17-one(27246-06-6)

Safety Data

• Hazardous Substances Data: 27246-06-6(Hazardous Substances Data)

Upstream product

• 1245018-82-9 3-trityloxy-17-methoxyandrostane 
• 481-29-8 Epiandrosterone 
• 76-83-5 trityl chloride 

Relevant articles and documents

CCl3CN: A crucial promoter of M CPBA-mediated direct ether oxidation

The direct oxidation of ether sp3 C-H bonds using the new reagent system mCPBA/CCl3CN/MeCN has been developed. CCl 3CN in MeCN drastically alters the reactivity of m-chloroperbenzoic acid (mCPBA), and chemoselective transformation of methyl ethers to ketones was realized under mild conditions. Radical-based mCPBA-mediated oxidation was suggested as the reaction mechanism. The present new reaction expands the utility of methyl ethers as stable synthetic precursors of carbonyl compounds and of mCPBA as a radical-based C-H oxidizing agent.