27301-80-0Relevant academic research and scientific papers
Mode of alkylation of alcohols with O-cyclopropylmethyl trichloroacetimidate and O-cyclobutyl trichloroacetimidate
Ali, Ibrahim A.I.,Zhu, Xiangming,El Ashry, El Sayed H.,Schmidta, Richard R.
experimental part, p. 35 - 44 (2012/03/09)
Acid promoted alkylation of hydroxy group containing acceptors 3-14 with O-cyclopropylmethyl and O-cyclobutyl trichloroacetimidates 1 and 2, respectively, afforded ethers with cyclopropylmethyl, cyclobutyl, and homoallyl residues as a result of the rearrangement of the cation intermediates. The dependence of product formation on acceptor structure is discussed. ARKAT-USA, Inc.
