27323-98-4

Basic information

• Product Name: (C₆H₅)3SnV(CO)6
• Synonyms: (C₆H₅)3SnV(CO)6
• CAS NO: 27323-98-4
• Molecular Weight: 569.031
• Mol File: 27323-98-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (C₆H₅)3SnV(CO)6(CAS DataBase Reference)
• NIST Chemistry Reference: (C₆H₅)3SnV(CO)6(27323-98-4)
• EPA Substance Registry System: (C₆H₅)3SnV(CO)6(27323-98-4)

Safety Data

• Hazardous Substances Data: 27323-98-4(Hazardous Substances Data)

Upstream product

• 639-58-7 triphenyltin chloride 
• 15602-41-2 sodium hexacarbonylvanadate 
• 14024-00-1 vanadium hexacarbonyl 
• 892-20-6 triphenylstannane 
• 20644-87-5 (hexacarbonyl)vanadinate^(1-) 

Downstream Products

• 20644-87-5 (hexacarbonyl)vanadinate^(1-) 
• 10170-61-3 tetraethyl ammonium pentacarbonyl (triphenyl phosphine) vanadat 
• 12114-33-9 (CO)6V*AuP(C₆H₅)3=(CO)6VAuP(C₆H₅)3 
• 14024-00-1 vanadium hexacarbonyl 

Relevant articles and documents

VANADIUM-METAL BONDS IN CARBONYLVANADIUM COMPLEXES: A 51V NMR SPECTROSCOPIC INVESTIGATION

The complexes (ERm =SnPh3, SnEt3, PbPh3, AuPPh3), and 2 (E=Sn, Pb), and 5-C5H5)(EPh3)(CO)3>(E=Si, Ge, Sn, Pb) have been prepared and investigated by 51V NMR spectroscopy.Shielding of the vanadium nucleus decreases in the order Sn>Ge>Si>Pb as a result of counteracting effects upon the paramagnetic deshielding term.The trends are discussed in the general context of molecular parameters (polarizability, covalency, electronegativity, and ligand strength) influencing metal shielding in transition metal carbonyl derivatives.In the case of , ion pair formation (+-) rather than seven-coordination is predicted. 5-C5H5)(SnPh3)(CO)3>- extends the low-frequency region of the δ(51V) scale to -2054 ppm relative to VOCl3.