27333-96-6

Basic information

• Product Name: CH₃CH₂NHCSP(S)(C₆H₅)2
• CAS NO: 27333-96-6
• Molecular Weight: 305.404
• Mol File: 27333-96-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: CH₃CH₂NHCSP(S)(C₆H₅)2(CAS DataBase Reference)
• NIST Chemistry Reference: CH₃CH₂NHCSP(S)(C₆H₅)2(27333-96-6)
• EPA Substance Registry System: CH₃CH₂NHCSP(S)(C₆H₅)2(27333-96-6)

Safety Data

• Hazardous Substances Data: 27333-96-6(Hazardous Substances Data)

Upstream product

• 542-85-8 Ethyl isothiocyanate 
• 6591-07-7 diphenylphosphane sulfide 

Downstream Products

• 80537-22-0 tetracarbonyl(diphenylthiophosphinyl-N-ethylthioformimidato-S,S')rhenium 
• 80537-19-5 tetracarbonyl(diphenylthiophosphinyl-N-ethylthioformimidato-S,S')manganese 

Relevant articles and documents

Phosphine Substituted Chelate Ligands, II. Thiocarbamoylphosphine Sulfide and Oxide Complexes of Manganese and Rhenium

Thiocarbamoylphosphine sulfides 1a-c and oxides 2a-c are ambidentate chelating ligands which may form monomeric or dimeric complexes with carbonylmetal halides.The reaction of 1a-c with ClMn(CO)5 and ClRe(CO)5 yields the monomeric cis-tetracarbonyl complexes 3a-c and 4a-c with S,S'-coordination.The phosphine oxides 2a-c first form tetracarbonyl complexes which dimerize spontaneously under loss of CO to give the anti-fac-tricarbonyl complexes 5a-c and 6a with bridging three-coordinate sulfur.On refluxing in n-hexane solution, 3a-c and 4b,c are converted into the corresponding dimers 7a-c and 8b,c.Dissolving of 7b, c in CH2Cl2 leads to re-formation of 3b, c, the free ligands 1b, c and inorganic manganese compounds. - Keywords: Chelate Ligands, Thiocarbamoylphosphine Sulfide, Thiocarbamoylphosphine Oxide, Manganese Complexes, Rhenium Complexes