27356-60-1Relevant academic research and scientific papers
Synthesis of frans-2-(1-aryl-1-methylethyl)cyclohexylamines
Lee, Wen-Yee,Salvador, James M.,Bodige, Kalavathi
, p. 931 - 932 (2000)
(equation presented) As a first example of opening a secondary aziridine with a tertiary carbanion, the title amines (3a-c, aryl = phenyl, 4-tert-butylphenyl, 2-naphthyl) were synthesized by opening N-(diphenylphosphinoyl)-7-azabicyclo[4.1.0]heptane, aziridine 1, with the corresponding α-potassium isopropylarenes, followed by hydrolysis of the resulting phosphinamides 2a-c.
