27374-23-8

Basic information

• Product Name: Silane, [1-(dimethylphenylsilyl)ethenyl]trimethyl-
• CAS NO: 27374-23-8
• Molecular Formula: C13H22Si2
• Molecular Weight: 234.489
• Mol File: 27374-23-8.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Silane, [1-(dimethylphenylsilyl)ethenyl]trimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, [1-(dimethylphenylsilyl)ethenyl]trimethyl-(27374-23-8)
• EPA Substance Registry System: Silane, [1-(dimethylphenylsilyl)ethenyl]trimethyl-(27374-23-8)

Safety Data

• Hazardous Substances Data: 27374-23-8(Hazardous Substances Data)

Upstream product

• 766-77-8 Dimethylphenylsilane 
• 1066-54-2 trimethylsilylacetylene 
• 49750-22-3 1-(trimethylsilyl)vinylmagnesium bromide 
• 768-33-2 phenyldimethylsilyl chloride 
• 891859-21-5 1-(ethoxydimethylsilyl)-1-(dimethylphenylsilyl)ethene 
• 917-64-6 methyl magnesium iodide 
• 1125-26-4 dimethylphenylvinylsilane 

Relevant articles and documents

Construction of highly sterically hindered 1,1-disilylated terminal alkenes

One direct and efficient procedure for the synthesis of 1,1-disilylated terminal alkenes is demonstrated in this paper. To overcome and rationally utilize the steric hindrance of silyl units, the cationic ruthenium catalyst [CpRu(MeCN)3]+ was found to be effective for Markovnikov hydrosilylation of 1-silyl terminal alkynes with high yields and excellent regioselectivity. Dissimilarities between alkyl and alkoxy silyl units lead to versatile product derivatizations toward a variety of useful building blocks.

Silver-catalyzed transmetalation between chlorosilanes and aryl and alkenyl Grignard reagents for the synthesis of tetraorganosilanes

(Chemical Equation Presented) The silver savior: Nucleophilic substitution reactions of chlorosilanes with aryl Grignard reagents have been developed which take place under silver catalysis to afford tetraorganosilanes (see scheme). This transformation is likely to be promoted by diarylargentate reagents that are generated in situ.

Insertion of Vinylsilane into the Ruthenium-Silicon-Bond - Direct Evidence for the Non-metallacarbene Mechanism of Silylalkene Disproportionation

The reversible insertion of the vinylsilane molecule into the Ru-Si bond occurs in two different ways to give E-1,2-bis(silyl)ethene and 1,1-bis(silyl)ethene which, in combination with the previous experiments by Wakatsuki et al., provides convincing evidence for a non-metallacarbene mechanism of silylalkene disproportionation.