273752-75-3Relevant academic research and scientific papers
Selective transformation of ascomycin into 11-epi-ascomycin
Baumann, Karl,Bacher, Markus,Damont, Annelaure,Steck, Andrea
, p. 549 - 551 (2004)
Within the binding domain, ascomycin features the unusual pattern of a masked tricarbonyl moiety, which potentially allows for high structural diversity via simple isomerisation events. A cascade of diastereoselective rearrangement reactions at the binding domain, allowing the conversion of ascomycin into 11-epi-ascomycin is herein reported.
