27396-56-1Relevant academic research and scientific papers
Lewis Base Mediated Polymorph Selectivity of Pyrite CuSe2 through Atom Transfer in Solid-State Metathesis
Martinolich, Andrew J.,Higgins, Robert F.,Shores, Matthew P.,Neilson, James R.
, p. 1854 - 1860 (2016)
Preparation of metastable solid-state materials is often hindered by the limitations of traditional solid-state chemistry, namely the high temperatures required to induce solid-state diffusion. Here, we present the formation of the metastable pyrite polym
New bioactive ferrocene-substituted heteroleptic copper(I) complex: Synthesis, structural elucidation, DNA interaction, and DFT study
Zubair, Shumaila,Asghar, Faiza,Badshah, Amin,Lal, Bhajan,Hussain, Raja Azadar,Tabassum, Saira,Tahir, Muhammad Nawaz
, p. 60 - 68 (2019)
In the present work, a new para-ferrocenylbenzoate copper(I) complex (a4) has been synthesized and characterized by numerous spectroscopic techniques such as: FT-IR, AAS, and CHNS analysis. Moreover, the single-crystal X-ray structure of the compound a4 was also explored. The DNA binding potency was determined by cyclic voltammetry, UV-visible spectroscopy, and viscometry. The redox behavior of the complex studied by cyclic voltammetry revealed a single quasi-reversible voltammogram, attributed to the dominant redox-active ferrocenyl moiety. The electrochemical study reveals that the complex binds to DNA non-covalently, the mode of interaction in particular, was found to be an electrostatic. The DNA binding constant was found to be 4.3 × 104 M?1, which is very significant and impressive for non-covalent interactions, and is in close agreement with the UV-visible spectroscopic results. DFT/B3LYP method was used to ascertain the energies of frontier molecular orbitals (HOMO/LUMO) and the charge distribution on the molecular structure. The ferrocene-based copper(I) complex (a4) demonstrated to be a decent candidate in terms of cytotoxicity, although less active than that of the standard chemotherapeutic drug (cisplatin).
Catalytic one-pot three-component synthesis of 3,3′-disubstituted oxindoles and spirooxindole pyrans by mixed ligand transition metal complexes
Hegade, Sujit,Gaikwad, Gautam,Jadhav, Yuvraj,Pore, Avinash,Mulik, Abhijeet
, p. 95 - 103 (2021/11/22)
Abstract: New three-component reaction was developed via one-pot strategy for the synthesis of functionalized 3,3′-disubstituted oxindoles and spirooxindole through the reaction among isatin, malononitrile, and acetone/indole/nitromethane/acetylacetone/di
