27427-48-1

Upstream product

• 13462-88-9 nickel dibromide 
• 22031-12-5 [2-((diphenylphospino)methyl)-2-methyl-1,3-propanediyl]bis[diphenylphosphine] 
• 28923-39-9 nickel(II) bromide dimethoxyethane 
• 157617-60-2 3-(diphenylphosphino)-2-(diphenylphosphino)methyl-2-methylpropanol 

Downstream Products

• 1142409-01-5 [(tripod)Ni(C₂H₄)] 
• 1142409-00-4 [(tripod)Ni(tBuNC)] 
• 1142408-99-8 [(tripod)Ni(cHexNC)] 
• 1142408-98-7 [(tripod)NiAsPh₃] 
• 1142408-97-6 [(tripod)NiPPh₃] 
• 1142425-73-7 [(1,1,1-tris((diphenylphosphanyl)methyl)ethane)NiSePh] 
• 1142425-72-6 [(1,1,1-tris((diphenylphosphanyl)methyl)ethane)NiS(tBu)] 

Relevant academic research and scientific papers

Modulating sonogashira cross-coupling reactivity in four-coordinate nickel complexes by using geometric control

Herein, we present the synthesis of nickel complexes with tripodal phosphine ligands, CH3Si(CH2PPh2)3 and CH3C(CH2PPh2)3, and their application as catalysts in Sonogas

Reductive activation of tripod metal compounds: Identification of intermediates and preparative application

[tripodCoCl2] {tripod = CH3C(CH2PPh 2)3} when treated with KC8 in THF solution under an argon atmosphere produces a reactive species ["tripodCo 0"] (A) which undergoes oxidative

Reductive activation of tripod metal compounds: Preparative application

The tripodnickel(0) species [tripod4Ni3] (1) {tripod = CH3C(CH2PPPh2)3} is shown to undergo oxidative addition with disulfides or diselenides REER (E = S, Se, R = tBu, Ph) to produce [tripo

Tripod Ligands with Two Different Donor Groups: Synthesis and Coordination of H3CC(CH2PPh2)2(CH2OH)

Starting from pentaglycerin, H3C(CH2OH)3, a convenient three step synthesis of the tripod ligand H3CC(CH2PPh2)(CH2OH) (3) (abbreviated as PPO(H) is described and its structure is established by the ususal analytical methods as well as by X-ray analysis.The ligand behaves as a bidentate donor towards nickel(II) as shown by the formation and X-ray analysis of the complex NiBr2 (4).In the square planar complex 4 only the PPh2 groups are coordinated.In the tetrahedral complex 2Ni>(BF4)2 (5) two PPO(H) ligands surround nickel as bidentate ligands.Keywords: Mixed Donor Groups, Bidentate Phosphine Ligand, Nickel Complexes, Functionalized Neopentyl Compound, Oxetane Cleavage