274687-34-2Relevant academic research and scientific papers
Violet-blue emitting 2-(N-alkylimino)pyrrolyl organoboranes: Synthesis, structure and luminescent properties
Krishnamoorthy, Paramasivam,Ferreira, Bruno,Gomes, Clara S.B.,Vila-Vi?osa, Diogo,Charas, Ana,Morgado, Jorge,Calhorda, Maria José,Ma?anita, António L.,Gomes, Pedro T.
, p. 520 - 532 (2017)
The condensation reactions of 2-formylpyrrole (1) or 2-formylphenanthro[9,10-c]pyrrole (2) with various aliphatic amines afforded the corresponding 2-iminopyrrole ligand precursors 3–10, which, upon stoichiometric reaction with BPh3, led to the
Living ethylene/norbornene copolymerisation catalyzed by titanium complexes having two pyrrolide-imine chelate ligands
Yoshida, Yasunori,Saito, Junji,Mitani, Makoto,Takagi, Yukihiro,Matsui, Shigekazu,Ishii, Sei-Ichi,Nakano, Takashi,Kashiwa, Norio,Fujita, Terunori
, p. 1298 - 1299 (2002)
Ethylene/norbornene copolymerisation behaviour of titanium complexes with two pyrrolide-imine chelate ligands is described.
Titanium complexes of pyrrolylaldiminate ligands and their exploitation for the ring-opening polymerization of cyclic esters
Chuawong, Pitak,Hormnirun, Pimpa,Nanok, Tanin,Upitak, Kanokon,Wattanathana, Worawat
, p. 10964 - 10981 (2021/08/17)
A series of six-coordinate titanium complexes1-6supported by pyrrolylaldiminate ligands were preparedviathe reaction of 2 equivalents of ligands and Ti(OiPr)4in toluene at 70 °C. The X-ray structure of2revealed that the two ligands w
Hydrogen-Bond Catalysis of Imine Exchange in Dynamic Covalent Systems
Schaufelberger, Fredrik,Seigel, Karolina,Ramstr?m, Olof
, p. 15581 - 15588 (2020/10/02)
The reversibility of imine bonds has been exploited to great effect in the field of dynamic covalent chemistry, with applications such as preparation of functional systems, dynamic materials, molecular machines, and covalent organic frameworks. However, acid catalysis is commonly needed for efficient equilibration of imine mixtures. Herein, it is demonstrated that hydrogen bond donors such as thioureas and squaramides can catalyze the equilibration of dynamic imine systems under unprecedentedly mild conditions. Catalysis occurs in a range of solvents and in the presence of many sensitive additives, showing moderate to good rate accelerations for both imine metathesis and transimination with amines, hydrazines, and hydroxylamines. Furthermore, the catalyst proved simple to immobilize, introducing both reusability and extended control of the equilibration process.
Synthesis, characterization and cancer cell growth inhibition activity of ruthenium(II) complexes bearing bidentate pyrrole-imine ligands
Chen, Guan-Hao,Leu, Wohn-Jenn,Guh, Jih-Hwa,Lin, Chia-Her,Huang, Jui-Hsien
, p. 122 - 130 (2018/05/28)
A series of bidentate pyrrole-imine ligands, [C4H3NH-(2-CH=N-R)] (1, R = cyclohexenyl; 2, R = CH2CH2-1-cyclohexenyl; 3, R = tBu; 4, R = CH2-2-furyl; 5, R = 2-methoxylphenyl; 6, R = phenyl;
PHOSPHORESCENT IRIDIUM COMPLEXES
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Paragraph 0052; 0053; 0054, (2016/10/17)
Metal complexes of formula I and IA and polymers derived from the complexes are useful in optoelectronic devices wherein M is Ir, Co or Rh; is a cyclometallated ligand; R1 is hydrogen, alkyl, substituted alkyl, aryl, substituted aryl, arylalkyl, or substi
Novel vanadium(iii) complexes with bidentate N,N-chelating iminopyrrolide ligands: Synthesis, characterization and catalytic behaviour of ethylene polymerization and copolymerization with 10-undecen-1-ol
Xu, Bao-Chang,Hu, Tao,Wu, Ji-Qian,Hu, Ning-Hai,Li, Yue-Sheng
body text, p. 8854 - 8863 (2010/02/16)
A series of novel vanadium(iii) complexes bearing iminopyrrolide chelating ligands [2-(RNCH)C4H3N]V(THF)2Cl2 (2a: R = cyclohexyl; 2b: R = Ph; 2c: R = 2,6-iPr2C6H 3; 2d: R = p-CF
