274691-54-2

Upstream product

• 86-74-8 9H-carbazole 
• 607-81-8 diethyl 2-benzylmalonate 

Downstream Products

• 100433-89-4 5-benzyl-5-nitro-4H-pyrido[3,2,1-jk]carbazole-4,6(5H)-dione 
• 100773-91-9 5-benzyl-5-chloro-4H-pyrido[3,2,1-jk]carbazole-4,6(5H)-dione 
• 959575-30-5 5-azido-5-benzyl-4H-pyrido[3,2,1-jk]carbazole-4,6(5H)-dione 
• 893613-82-6 1-(9H-carbazol-1-yl)-2-hydroxy-3-phenylpropan-1-one 
• 893619-20-0 C₂₂H₁₅NO₃ 

Relevant academic research and scientific papers

Synthesis and reactions of pyrido[3,2,1-jk]carbazole-4,6-diones

Pyrido[3,2,1-jk]carbazoles 1, synthesized from carbazoles and alkyl- or arylmalonates, gave regioselective electrophilic substitution reactions at position 5 such as chlorination to 5-chloro derivatives 2, nitration to 5-nitro compounds 3, or hydroxylatio

Synthesis and ring closure reactions of pyrido[3,2,1-jk]carbazol-6-ones[1]

4-Hydroxy-5-phenylpyrido[32,1-jk]carbazol-6-ones (4, 5), which were obtained from carbazoles 1 and malonates 2 or 3, were converted to reactive intermediates such as 4-chlorides 9 or 4-tosylates 10, which gave in turn 4-azido-5-phenyl derivatives 11.5-Alkyl-4-azides 11 were not obtained in this manner; however a new one-pot azidation reaction was developed starting from 4-hydroxy derivatives 4 which gave azides 11 in good yields. 4-Azido-5-phenyl derivative 11f cyclized on thermolysis to the indole 12. The thermal behaviour of the azides 11 was studied by thermoanalytical methods (DSC).