2747-38-8

Basic information

• Product Name: trichlorotitanium
• Synonyms: Methyltitanium(IV)trichloride (6CI); Titanium, trichloromethyl- (7CI,8CI); Methyltitaniumchloride; Methyltitanium trichloride; Methyltrichlorotitanium;Trichloromethyltitanium
• CAS NO: 2747-38-8
• Molecular Formula: CH₃Cl₃Ti
• Molecular Weight: 0
• Mol File: 2747-38-8.mol
• Article Data: 4

Chemical Properties

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Appearance: /
• Density: g/cm³
• CAS DataBase Reference: trichlorotitanium(CAS DataBase Reference)
• NIST Chemistry Reference: trichlorotitanium(2747-38-8)
• EPA Substance Registry System: trichlorotitanium(2747-38-8)

Safety Data

• Hazardous Substances Data: 2747-38-8(Hazardous Substances Data)

Usage

InChI:InChI=1/CH3.3ClH.Ti/h1H3;3*1H;/q-1;;;;+4/p-3/rCH3.Cl3Ti/c;1-4(2)3/h1H3;/q-1;+1

Upstream product

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Relevant articles and documents

Symmetrical Distortion of the Methyl Group of Methyltrichlorotitanium: Gas Phase Structure and H,H Coupling Constant

Electron-diffraction studies show gaseous TiMeCl3 to have a symmetrically 'flattened' (C3v) methyl group with an H-C-Ti angle of 101.0+/-2.2 deg, which is reflected in solution by a most unusual large positive H,H coupling constant of +11.3 Hz; these data are interpreted in terms of a ?-donor interaction of methyl C-H bonds with low-lying metal d-orbitals.

2 -ARYLAMINOQUINAZOLINES FOR TREATING PROLIFERATIVE DISEASES

The invention provides novel compounds that are inhibitors of PDKI. Also provided are pharmaceutical compositions including the compounds, and methods of treating proliferative diseases, such as cancers, with the compounds or composition.