274905-39-4

Basic information

• Product Name: 2H-Pyran-2-one,tetrahydro-4-hydroxy-3-methyl-6-(1-methylethyl)-,(3R,4R,6S)-(9CI)
• Synonyms: 2H-Pyran-2-one,tetrahydro-4-hydroxy-3-methyl-6-(1-methylethyl)-,(3R,4R,6S)-(9CI)
• CAS NO: 274905-39-4
• Molecular Formula: C9H16O3
• Molecular Weight: 172.22
• Product Categories: ISOPROPYL
• Mol File: 274905-39-4.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 299.6±23.0 °C(Predicted)
• Appearance: /
• Density: 1.056±0.06 g/cm3(Predicted)
• PKA: 13.51±0.60(Predicted)
• CAS DataBase Reference: 2H-Pyran-2-one,tetrahydro-4-hydroxy-3-methyl-6-(1-methylethyl)-,(3R,4R,6S)-(9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: 2H-Pyran-2-one,tetrahydro-4-hydroxy-3-methyl-6-(1-methylethyl)-,(3R,4R,6S)-(9CI)(274905-39-4)
• EPA Substance Registry System: 2H-Pyran-2-one,tetrahydro-4-hydroxy-3-methyl-6-(1-methylethyl)-,(3R,4R,6S)-(9CI)(274905-39-4)

Safety Data

• Hazardous Substances Data: 274905-39-4(Hazardous Substances Data)

Upstream product

• 274905-27-0 (3R,5S)-2-Bromo-3-hydroxy-2,6-dimethyl-5-trimethylsilanyloxy-heptanoic acid ethyl ester 
• 274905-31-6 2-Bromo-2-((4R,6S)-6-isopropyl-2,2-dimethyl-[1,3]dioxan-4-yl)-propionic acid ethyl ester 
• 370868-25-0 ethyl (2R,3R,5S)-2-bromo-3-hydroxy-2,6-dimethyl-5-trimethylsiloxyheptanoate 
• 370868-29-4 ethyl (2R,3R,5S)-2-bromo-3,5-isopropylidenedioxy-2,6-dimethylheptanoate 
• 274905-22-5 (S)-4-Methyl-3-trimethylsilanyloxy-pentanoic acid ethyl ester 
• 274905-24-7 (3S)-4-methyl-3-trimethylsiloxypentanal 
• 182417-51-2 ethyl (3R)-2,2-(ethylenedithio)-3-hydroxy-4-methylpentanoate 
• 95614-85-0 ethyl (3S)-3-hydroxy-4-methylpentanoate 
• 274905-36-1 ethyl (2R,3R,5S)-3,5-isopropylidenedioxy-2,6-dimethylheptanoate 
• 274905-28-1 (3S,5S)-2-Bromo-3-hydroxy-2,6-dimethyl-5-trimethylsilanyloxy-heptanoic acid ethyl ester 
• 274905-29-2 2-Bromo-2-((4S,6S)-6-isopropyl-2,2-dimethyl-[1,3]dioxan-4-yl)-propionic acid ethyl ester 
• 370868-23-8 ethyl (2R,3S,5S)-2-bromo-3-hydroxy-2,6-dimethyl-5-trimethylsiloxyheptanoate 
• 370868-27-2 ethyl (2R,3S,5S)-2-bromo-3,5-isopropylidenedioxy-2,6-dimethylheptanoate 
• 274905-34-9 ethyl (2S,3S,5S)-3,5-isopropylidenedioxy-2,6-dimethylheptanoate 

Relevant articles and documents

An efficient method for the synthesis of enantiopure 2,3-anti-propionate aldols involving a 3,5-syn- or anti-diol subunit through chiral borane- mediated enantioselective aldol reaction coupled with radical reduction

2,3-anti-Propionate aldols involving a 3,5-syn- or anti-diol subunit, versatile enantiopure segments available for macrolide synthesis, were prepared by a chiral oxazaborolidinone-promoted asymmetric aldol reaction with 2-bromo-1-ethoxy-2-methyl-1-trimethylsiloxyethene and the following highly anti-preferential radical debromination. (C) 2000 Elsevier Science Ltd.