27491-23-2Relevant academic research and scientific papers
A novel thiochromone-type photolabile protecting group for carbonyl compounds
Sugiura, Ryo,Kozaki, Rikio,Kitani, Satoru,Gosho, Yoshinori,Tanimoto, Hiroki,Nishiyama, Yasuhiro,Morimoto, Tsumoru,Kakiuchi, Kiyomi
, p. 3984 - 3990 (2013/07/05)
A novel photolabile protecting group, thiochromone S,S-dioxide, possessing the 1,2-diol group for protection of ketones and aldehydes is described. Photodeprotection of the successfully protected carbonyl derivatives proceeded smoothly under photoirradiation filtered through Pyrex glass (>280 nm) using an ultrahigh-pressure mercury lamp to recover the corresponding carbonyl compounds and the starting protecting group.
