27508-85-6

Usage

Synthesis Reference(s)

The Journal of Organic Chemistry, 48, p. 3347, 1983 DOI: 10.1021/jo00167a045Tetrahedron, 61, p. 4989, 2005 DOI: 10.1016/j.tet.2005.03.048

InChI:InChI=1/C10H11NO2/c1-12-8-5-7-3-4-11-10(7)9(6-8)13-2/h3-6,11H,1-2H3

Upstream product

• 88106-84-7 β-(3,5-Dimethoxyphenyl)ethanesulfonyl azide 

Downstream Products

• 853133-56-9 1-benzyl-5,7-dimethoxyindole 
• 866319-40-6 2-(5,7-dimethoxy-1H-indol-3-yl)-1-(toluene-4-sulfonyl)-1H-pyrrolo[2,3-b]pyridine 
• 866319-39-3 2-(5,7-dimethoxy-1-methyl-1H-indol-3-yl)-1-(toluene-4-sulfonyl)-1H-pyrrolo[2,3-b]pyridine 
• 1269920-12-8 3-acetyl-5,7-dimethoxy-1-(4-fluorobenzyl)-1H-indole 
• 1269920-17-3 ethyl 4-[1-(4-fluorobenzyl)-5,7-dimethoxy-1H-indol-3-yl]-2-hydroxy-4-oxobut-2-enoate 
• 1269920-22-0 4-[1-(4-fluorobenzyl)-5,7-dimethoxy-1H-indol-3-yl]-2-hydroxy-4-oxobut-2-enoic acid 

Relevant academic research and scientific papers

Diaryliodonium Salt-Mediated Intramolecular C-N Bond Formation Using Boron-Masking N-Hydroxyamides

Intramolecular aromatic C-N bond formation reactions using electron-rich aromatic tethered boron-masking N-hydroxyamide as substrate were realized. These new C-N bond formation reactions involve the in situ generation of a diaryliodonium salt by treatment with hypervalent iodine, deborylation by base treatment, spontaneous N → O acyl migration, cyclization, reductive elimination, elimination of benzoic acid, and tautomerization to indole formation. Hereby, we obtained highly functionalized electron-rich indoles and quinoline in practical yields.

Solution and Flash Vacuum Pyrolyses of β-(3,5-Disubstituted-phenyl)ethanesulfonyl Azides. Sultam, Pyrindine, and Azepine Formation

The solution and flash vacuum pyrolyses of β-(3,5-disubstituted-phenyl)ethanesulfonyl azides are reported.When R = Me, FVP results suggest that the substituents stabilize the intermediate leading to the 3,4-dihydro-2,1-benzothiazepine 2,2-dioxide (6a).A n