275826-01-2Relevant academic research and scientific papers
The first total synthesis of (±)-grimaldone
Srikrishna,Ramachary
, p. 2231 - 2233 (2000)
The first total synthesis of (±)-grimaldone, a tricyclic sesquiterpene containing three contiguous quaternary carbon atoms, and (±)-epigrimaldone along with (±)-α-cuparenone starting from Hagemann's ester is described. (C) 2000 Elsevier Science Ltd.
Total synthesis of (±)-grimaldone, epigrimaldone and α-cuparenones
Srikrishna,Ramachary
, p. 1216 - 1226 (2007/10/03)
Total synthesis of (±)-grimaldone, epigrimaldone and α-cuparenone has been described. A combination of orthoester Claisen rearrangement, an acid catalysed rearrangement of a diazoketone for the generation of bicyclo[4.2.1]nonanedione, a retro-Claisen cond
