27628-05-3

Basic information

• Product Name: Ethanone, 1-[3,4-bis(phenylmethoxy)phenyl]-2-bromo-
• CAS NO: 27628-05-3
• Molecular Formula: C22H19BrO3
• Molecular Weight: 411.295
• Mol File: 27628-05-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Ethanone, 1-[3,4-bis(phenylmethoxy)phenyl]-2-bromo-(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 1-[3,4-bis(phenylmethoxy)phenyl]-2-bromo-(27628-05-3)
• EPA Substance Registry System: Ethanone, 1-[3,4-bis(phenylmethoxy)phenyl]-2-bromo-(27628-05-3)

Safety Data

• Hazardous Substances Data: 27628-05-3(Hazardous Substances Data)

Upstream product

• 99-93-4 4-Hydroxyacetophenone 
• 1836-06-2 3-bromo-4-hydroxyacetophenone 
• 1197-09-7 1-(3,4-dihydroxyphenyl)ethan-1-one 
• 5878-50-2 3,4-bis(benzyloxy)acetophenone 
• 27628-06-4 1-(3,4-bis(benzyloxy)phenyl)ethan-1-one 

Downstream Products

• 95484-11-0 3,4-bis(benzyloxy)-α-acetophenone 
• 67631-92-9 2-[1,1-dimethyl-2-(2-phenoxyacetamido)ethylamino]-3',4'-bispivaloyloxy acetophenone trifluoroacetate 
• 36611-54-8 N-benzyl-N-(3,4-dibenzyloxybenzoyl)methyl-2-(4-carbamoylphenoxy)-ethylamine 
• 1292298-96-4 2-(3,4-bis(benzyloxy)phenyl)-2-oxoethyl-4-(tert-butoxycarbonylamino)butanoate 
• 36665-77-7 4-(2-{Benzyl-[2-(3,4-bis-benzyloxy-phenyl)-2-hydroxy-ethyl]-amino}-ethoxy)-benzamide 
• 56443-14-2 1-{2-[2-(3,4-Dihydroxy-phenyl)-2-hydroxy-ethylamino]-ethyl}-3-phenyl-urea 
• 56443-18-6 1-(3,4-dihydroxyphenyl)-2-(β-isobutyramidoethyl)aminoethanol 
• 82832-84-6 1-{1-[2-(3,4-Bis-benzyloxy-phenyl)-2-hydroxy-ethyl]-piperidin-4-yl}-1,3-dihydro-benzoimidazol-2-one; hydrochloride 
• 74178-86-2 1-<2-hydroxy-2-(3,4-dihydroxyphenyl)ethyl>-4-(1,3-dihydro-2H-benzimidazol-2-one-1-yl)piperidine hydrochloride 

Relevant articles and documents

P-Hydroxyphenacyl photoremovable protecting groups Robust photochemistry despite substituent diversity

A broadly based investigation of the effects of a diverse array of substituents on the photochemical rearrangement of p-hydroxyphenacyl esters has demonstrated that common substituents such as F, MeO, CN, CO2R, CONH2, and CH3 have little effect on the rate and quantum efficiencies for the photo-Favorskii rearrangement and the release of the acid leaving group or on the lifetimes of the reactive triplet state. A decrease in the quantum yields across all substituents was observed for the release and rearrangement when the photolyses were carried out in buffered aqueous media at pHs that exceeded the ground-state pKa of the chromophore where the conjugate base is the predominant form. Otherwise, substituents have only a very modest effect on the photoreaction of these robust chromophores.

Conformational effects on the activity of drugs. 11. Stereostructural models of the direct activation of the α- and β-adrenergic receptor

-