27628-22-4Relevant academic research and scientific papers
Kinetic analysis and sequencing of Si-H and C-H bond activation reactions: Direct silylation of arenes catalyzed by an iridium-polyhydride
Esteruelas, Miguel A.,Martínez, Antonio,Oliván, Montserrat,O?ate, Enrique
supporting information, p. 19119 - 19131 (2020/11/13)
The saturated trihydride IrH3{κ3-P,O,P-[xant(PiPr2)2]} (1; xant(PiPr2)2 = 9,9-dimethyl-4,5-bis(diisopropylphosphino)xanthene) coordinates the Si-H bond of triethylsilane, 1,1,1,3,5,5,5-heptamethyltrisiloxane, and triphenylsilane to give the σ-complexes Ir
Silylation of aryl iodides with 1,1,1,3,5,5,5-heptamethyltrisiloxane catalyzed by transition-metal complexes
Murata, Miki,Ota, Kosuke,Yamasaki, Hiroyuki,Watanabe, Shinji,Masuda, Yuzuru
, p. 1387 - 1390 (2008/02/13)
The silylation of various kinds of aryl iodides with 1,1,1,3,5,5,5- heptamethyltrisiloxane was achieved by a suitable transition-metal catalyst, such as Pd(0), Pt(0), and Rh(I). These catalytic systems showed dramatically different substrate scope. Georg Thieme Verlag Stuttgart.
Method for the cleavage of organic siloxanes, and products and applications thereof
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, (2008/06/13)
A method for the cleavage of organosiloxanes with chlorosilanes in the presence of ferric chloride and hydrogen chloride as catalysts resulting in chloroalkyl silanes or chloroaryl silanes, and organosiloxanes, which are characterized by one or more --O--Si--R3 groups, (R=alkyl or aryl), which are directly bound to a silicon atom which in turn is bound either to the same grouping or to an alkyl or aryl moiety.
