27640-10-4Relevant academic research and scientific papers
Accelerated SuFEx Click Chemistry For Modular Synthesis**
Barrow, Andrew S.,Gialelis, Timothy L.,Homer, Joshua A.,Koelln, Rebecca A.,Moses, John E.,Smedley, Christopher J.
supporting information, (2021/12/10)
SuFEx click chemistry is a powerful method designed for the selective, rapid, and modular synthesis of functional molecules. Classical SuFEx reactions form stable S?O linkages upon exchange of S?F bonds with aryl silyl-ether substrates, and while near-per
Decarboxylative cross-coupling of aryl tosylates with aromatic carboxylate salts
Goossen, Luksa J.,Rodriguez, Nuria,Lange, Paul P.,Linder, Christophe
supporting information; experimental part, p. 1111 - 1114 (2010/04/29)
(Figure Presented) A bimetallic copper/palladium catalyst system is disclosed that enables the use of tosylates as carbon electrophiles in decarboxylative coupling reactions. A variety of aromatic carboxylate salts, regardless of their substitution pattern, have been coupled with these inexpensive and readily available electrophiles to give the corresponding biaryl compounds in good yields (see scheme).
