276681-04-0

Basic information

• Product Name: Silane, [[(2E)-3-(2,5-dimethoxyphenyl)-1-methylene-2-propenyl]oxy](1,1-dimeth ylethyl)dimethyl-
• CAS NO: 276681-04-0
• Molecular Formula: C18H28O3Si
• Molecular Weight: 320.504
• Mol File: 276681-04-0.mol

Chemical Properties

• CAS DataBase Reference: Silane, [[(2E)-3-(2,5-dimethoxyphenyl)-1-methylene-2-propenyl]oxy](1,1-dimeth ylethyl)dimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, [[(2E)-3-(2,5-dimethoxyphenyl)-1-methylene-2-propenyl]oxy](1,1-dimeth ylethyl)dimethyl-(276681-04-0)
• EPA Substance Registry System: Silane, [[(2E)-3-(2,5-dimethoxyphenyl)-1-methylene-2-propenyl]oxy](1,1-dimeth ylethyl)dimethyl-(276681-04-0)

Safety Data

• Hazardous Substances Data: 276681-04-0(Hazardous Substances Data)

Upstream product

• 69739-34-0 t-butyldimethylsiyl triflate 
• 118709-30-1 trans-1-(2,5-dimethoxyphenyl)-2-buten-3-one 
• 93-02-7 2,5-dimethoxybenzaldehyde 

Downstream Products

• 276681-37-9 2-methyl-9-methoxy-4-(2,5-dimethoxyphenyl)-6H-pyrrolo[3,4-c]carbazole-1,3-dione 

Relevant articles and documents

Open analogues of arcyriaflavin A. Synthesis through Diels-Alder reaction between maleimides and 1-aryl-3-tert-butyldimethylsiloxy-1,3- butadienes

The preparation of a range of open analogues of arcyriaflavin A is described. The synthetic approach is based on the use of perhydroisoindole- 1,3,5-triones as key intermediates, which were obtained via Diels-Alder methodology using 1-aryl-3-siloxy-1,3-butadienes as starting materials. Fischer indolization and aromatization processes afforded different methoxy- substituted arylpyrrolocarbazoles. The stereochemistry and conformation of the Diels-Alder products and the regiochemistry of the indolization reactions are supported by NMR and molecular modeling studies.