276870-70-3

Basic information

• Product Name: 2-diazo-malonic acid 2-(tert-butyl-diphenyl-silanyloxymethyl)-5-(2,4-dioxo-3,4-dihydro-2H-pyrimidin-1-yl)-tetrahydro-furan-3-yl ester ethyl ester
• CAS NO: 276870-70-3
• Molecular Weight: 606.707
• Mol File: 276870-70-3.mol

Chemical Properties

• CAS DataBase Reference: 2-diazo-malonic acid 2-(tert-butyl-diphenyl-silanyloxymethyl)-5-(2,4-dioxo-3,4-dihydro-2H-pyrimidin-1-yl)-tetrahydro-furan-3-yl ester ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 2-diazo-malonic acid 2-(tert-butyl-diphenyl-silanyloxymethyl)-5-(2,4-dioxo-3,4-dihydro-2H-pyrimidin-1-yl)-tetrahydro-furan-3-yl ester ethyl ester(276870-70-3)
• EPA Substance Registry System: 2-diazo-malonic acid 2-(tert-butyl-diphenyl-silanyloxymethyl)-5-(2,4-dioxo-3,4-dihydro-2H-pyrimidin-1-yl)-tetrahydro-furan-3-yl ester ethyl ester(276870-70-3)

Safety Data

• Hazardous Substances Data: 276870-70-3(Hazardous Substances Data)

Upstream product

• 951-78-0 2'-deoxyuridine 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 183269-46-7 1-[5-(tert-butyl-diphenyl-silanyloxymethyl)-4-hydroxy-tetrahydro-furan-2-yl]-1H-pyrimidine-2,4-dione 

Relevant articles and documents

Diastereoselective synthesis of α-substituted-γ-butyrolactones of nucleosides via [1,5]-c,h insertion reactions of α-diazomalonates of nucleosides

Diastereoselective and regioselective [1,5]-C,H insertion reactions of 2'-deoxy-3'-diazomalonate nucleosides afforded τ-butyrolactones of nucleosides as chiral synthons for the preparation of 2'-C-branched nucleosides.