27695-76-7

Basic information

• Product Name: C₉H₁₀NO₂
• CAS NO: 27695-76-7
• Molecular Weight: 164.184
• Mol File: 27695-76-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₉H₁₀NO₂(CAS DataBase Reference)
• NIST Chemistry Reference: C₉H₁₀NO₂(27695-76-7)
• EPA Substance Registry System: C₉H₁₀NO₂(27695-76-7)

Safety Data

• Hazardous Substances Data: 27695-76-7(Hazardous Substances Data)

Upstream product

• 874-60-2 4-methyl-benzoyl chloride 
• 1613-85-0 N-methyl-N-(4-methylbenzoyl)hydroxylamine 
• 124731-04-0 O-diphenylphosphino-N-methyl-4-toluohydroxamic acid 
• 124731-06-2 N-([1,3,2]Dioxaphospholan-2-yloxy)-4,N-dimethyl-benzamide 

Relevant articles and documents

The Reaction Between N-Methyl-p-toluohydroxamic Acid and Tervalent Phosphorous Compounds: a Thermal PIII -> PV Rearrangement proceeding by a Radical Mechanism

N-Methyl-p-toluohydroxamic acid (6) reacts rapidly with phosphorus compounds XYPCl (X = Ph, Y = OEt and X,Y = OCH2CH2O) at -60 deg C in the presence of pyridine to give the PIII intermediates (7) which have been characterised by 1H, 13C, and 31P n. m. r. spectroscopy.The intermediates decompose at ambient temperatures with homolysis of the N-O bond to give the isomeric N-phosphine oxides (8), accompanied by varying amounts of O-phosphonylhydroxamic acids (9) N-methyl-4-toluamide, (4) and phosphoryl-radical related products.Evidence for a radical-cage process (at least in part) is obtained from 1H and 31P CIDNP studies.