277311-11-2Relevant academic research and scientific papers
Synthesis of hindered silyl ethers via fragmentation reactions
Asadi, Mohammad G.,Safa, Kazem D.,Shamsi, Zahr A.
, p. 2073 - 2079 (2007/10/03)
Reaction of alcoholic sodium alkoxides with (Me3Si) 3CSi(C6H4-OMe-p)MeX have been performed. Main products are of the type: (Me3Si)2CHSi(An)Me(OR) and Me3SiCH2Si(An)Me(OR); An = (C6H 4-OMe-p) and OR = OEt, OPr, O iso-Pr, OBu, O iso-Bu, O iso-Amyl, OBenzyl, OAllyl, Ofurfuryl. It is suggested that the reaction proceeds through an elimination-addition mechanism.
