27767-56-2

Basic information

• Product Name: 2-((1S,2S)-2-Hydroxy-7-methoxy-8-methyl-1,2,3,4-tetrahydro-naphthalen-1-yl)-propionic acid
• Synonyms: 2-((1S,2S)-2-Hydroxy-7-methoxy-8-methyl-1,2,3,4-tetrahydro-naphthalen-1-yl)-propionic acid
• CAS NO: 27767-56-2
• Molecular Weight: 264.321
• Mol File: 27767-56-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-((1S,2S)-2-Hydroxy-7-methoxy-8-methyl-1,2,3,4-tetrahydro-naphthalen-1-yl)-propionic acid(CAS DataBase Reference)
• NIST Chemistry Reference: 2-((1S,2S)-2-Hydroxy-7-methoxy-8-methyl-1,2,3,4-tetrahydro-naphthalen-1-yl)-propionic acid(27767-56-2)
• EPA Substance Registry System: 2-((1S,2S)-2-Hydroxy-7-methoxy-8-methyl-1,2,3,4-tetrahydro-naphthalen-1-yl)-propionic acid(27767-56-2)

Safety Data

• Hazardous Substances Data: 27767-56-2(Hazardous Substances Data)

Upstream product

• 27982-94-1 1,2-epoxy-7-methoxy-8-methyl-1,2,3,4-tetrahydro-naphthalene 

Relevant articles and documents

NUCLEOPHILIC RING OPENING OF EPOXIDES BY CARBANIONS; NOVEL FORMATION OF CYCLOPROPANE DERIVATIVES IN A NON-POLAR SOLVENT

Nucleophilic ring-opening of epoxides 2(a-d) with carbanions of different steric requirements under refluxing benzene afforded a single stereoisomer of the cyclopropane derivatives 4.The same reaction under refluxing ethanol gave the normal products, i.e. the trans-lactones 6.Mechanism and high stereoselectivity observed in the novel cyclopropane formation, and regiospecific cleavage of the cyclopropane carboxylic acids (in 4) have also been discussed in detail.