277754-84-4Relevant academic research and scientific papers
Formal [(2+2)+2] and [(2+2)+(2+2)] nonconjugated dienediyne cascade cycloadditions
Wu, Yao-Ting,Linden, Anthony,Siegel, Jay S.
, p. 4353 - 4355 (2005)
(Chemical Equation Presented) Fluoranthene 2 and heptacycle 3 are easily accessible from the reaction of diyne 1 and norbornadiene (NBD) in the presence of the rhodium catalyst. The unusual [(2+2)+(2+2)] adduct 3 was confirmed by the X-ray crystal structu
Synthesis of fluoranthenes and indenocorannulenes: Elucidation of chiral stereoisomers on the basis of static molecular bowls
Wu, Yao-Ting,Hayama, Tomoharu,Baldridge, Kim K.,Linden, Anthony,Siegel, Jay S.
, p. 6870 - 6884 (2007/10/03)
Cycloaromatization of a peri diyne with an external alkyne provides a general route to indenofused polynuclear aromatics. Fluoranthenes 9 (or 13) are easily accessible in good to excellent yields (75-99%; 18 examples) from the reaction of symmetric (or as
Imposing curvature on a polyarene by intramolecular palladium-catalyzed arylation reactions: A simple synthesis of dibenzo[a,g]corannulene
Reisch, Helge A.,Bratcher, Matthew S.,Scott, Lawrence T.
, p. 1427 - 1430 (2007/10/03)
(Matrix Presented) Palladium catalysis has been found to offer an effective solution-phase alternative to gas-phase flash vacuum pyrolysis as a method for converting the planar ring system of 7,10-di(2-bromophenyl)fluoranthene (4) to that of the C28
