27808-23-7Relevant academic research and scientific papers
Reactions of pyrazolium salts with silyllithium reagents. Regioselective synthesis of 5-silylated 3-pyrazolines
Cuadrado, Purificacion,Gonzalez-Nogal, Ana M.
, p. 1449 - 1452 (1998)
1,3,5-trisubstituted-2-methylpyrazolium iodides react with dimethylphenylsilyl- and tert-butyldiphenylsilyllithium leading, in general, to one of the corresponding 5-silyl-3-pyrazolines. The silyl group is easily substituted by electrophiles to give 5-functionalized 3-pyrazolines. Moreover, 5-silyl-3-pyrazolines undergo thermic ring opening with silicon-rearrangement affording α-silylated β-diimines.
