278167-60-5

Basic information

• Product Name: 1-(p-toluenesulfonyl)-3-iodo-4-phenyl-1H-pyrrole
• Synonyms: 1-(p-toluenesulfonyl)-3-iodo-4-phenyl-1H-pyrrole
• CAS NO: 278167-60-5
• Molecular Weight: 423.274
• Mol File: 278167-60-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1-(p-toluenesulfonyl)-3-iodo-4-phenyl-1H-pyrrole(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(p-toluenesulfonyl)-3-iodo-4-phenyl-1H-pyrrole(278167-60-5)
• EPA Substance Registry System: 1-(p-toluenesulfonyl)-3-iodo-4-phenyl-1H-pyrrole(278167-60-5)

Safety Data

• Hazardous Substances Data: 278167-60-5(Hazardous Substances Data)

Upstream product

• 278167-19-4 1-(p-toluenesulfonyl)-3-trimethylsilyl-4-iodo-1H-pyrrole 
• 278167-52-5 1-(p-toluenesulfonyl)-3-trimethylsilyl-4-phenyl-1H-pyrrole 

Downstream Products

• 278167-59-2 1-(p-toluenesulfonyl)-3-phenyl-4-(trans-2-methoxycarbonylethenyl)-1H-pyrrole 
• 278167-61-6 1-(p-toluenesulfonyl)-3-(p-methoxyphenyl)-4-phenyl-1H-pyrrole 

Relevant articles and documents

CuI-Catalyzed Decarboxylative Thiolation of Propargylic Cyclic Carbonates/Carbamates to Access Allenyl Thioethers

The first CuI-catalyzed decarboxylative thiolation of terminal alkyne-substituted cyclic carbonates/carbamates to access allenes has been developed. A wide range of hydroxymethyl-and aminomethyl-containing allenyl thioethers were smoothly obtained in good to excellent yields under mild conditions. The copper-allenylidene intermediate among the process is crucial to the decarboxylative thiolation reaction. This method opens up a new channel to access allenyl thioether compounds.