278171-22-5Relevant academic research and scientific papers
Palladium-catalyzed arylation of methyl 2-(acetoxymethyl)acrylate: A convenient synthesis of rearranged Morita-Baylis-Hillman acetates
Kim, Ko Hoon,Lim, Jin Woo,Lee, Hyun Ju,Kim, Jae Nyoung
, p. 419 - 423 (2013/02/25)
Palladium-catalyzed arylation of methyl 2-(acetoxymethyl)acrylate with aryl iodides afforded the primary acetates of Morita-Baylis-Hillman adducts in good yields with high stereoselectivity under mild conditions (50°C).
The Baylis-Hillman reaction: One-pot stereoselective synthesis of methyl (2E)-3-aryl-2-hydroxymethylprop-2-enoates
Basavaiah,Padmaja,Satyanarayana
, p. 1662 - 1664 (2007/10/03)
A facile, simple and one-pot conversion of methyl 3-aryl-3-hydroxy-2-methylenepropanoates into methyl (2E)-3-aryl-2-hydroxymethylprop-2-enoates via the sequential treatment with acetic anhydride/trimethylsilyl trifluoromethanesulfonate (TMSOTf) and potassium carbonate/methanol is described.
TMSOTf-catalyzed stereoselective isomerization of acetates of the Baylis-Hillman adducts
Basavaiah, Deevi,Muthukumaran, Kannan,Sreenivasulu, Bandaru
, p. 545 - 548 (2007/10/03)
TMSOTf-catalyzed isomerization of acetates of the Baylis-Hillman adducts, i.e. methyl 3-acetoxy-3-aryl-2-methylenepropanoates and 3-acetoxy-3- aryl-2-methylenepropanenitriles pro-viding methyl (2E)-2-(acetoxymethyl)-3- arylprop-2-enoates and (2E)-2-(aceto
